ZCARUS 5, 329333 (1966)
WaterVapor Mixing Ratios Near the Cloudtops of Venus 1 GEORGE 0HRING GCA Corporation, Bedford, Massachusetts Communicated by Carl Sagan Received October 15, 1965 It has been argued that the observed amounts of water vapor in the Cytherean atmosphere are incompatible with the presence of an aqueous cloud. These arguments have been based upon a comparison of the water mixing ratios derived from the observations and the required saturation mixing ratio. In deriving the watervapor mixing ratios, it has been assumed that the watervapor mixing ratio is constant with altitude above the Cytherean cloudtop. In the present paper, it is shown that if the Cytherean watervapor mixing ratio decreases with altitude in an isothermal atmosphere at rates comparable to those in the Earth's upper troposphere, some of the observed amounts of water vapor, at the present state of our knowledge, are compatible with the presence of aqueous clouds on Venus.
I. INTRODUCTION F r o m an analysis of the nearinfrared reflection spectrum of the Cytherean clouds, B o t t e m a et al. (1964) have concluded t h a t the clouds are composed of ice crystals. Arguments against ice (or water) clouds on Venus have been given b y Sagan and Kellogg (1963) and, more recently, b y Chamberlain (1965). These arguments are based upon a comparison of the watervapor mixing ratio derived from the observations of w a t e r  v a p o r amounts above the Cythercan clouds and the required saturation mixing ratio for condensation at the observed cloudtop lemperatures. Such a comparison indicates t h a t the w a t e r  v a p o r mixing ratios are much below those required for condensation. However, the computations b y Sagan and Kellogg, and Chamberlain, are based upon the assumption t h a t the watervapor mixing ratio is constant with altitude above the clouds. This is not necessarily the case. In the E a r t h ' s atmosphere, for example, the watervapor mixing ratio
generally decreases with altitude. In this paper, we investigate whether condensation can occur at the cloudtops, if the waterv a p o r mixing ratio decreases with altitude at rates comparable to those in the E a r t h ' s atmosphere. 12. DISCUSSION The watervapor mixing ratio is defined as the ratio of the density of water v a p o r to the density of the dry atmosphere containing the water vapor. However, to a high degree of approximation, it can be represented as = p,/p,
(1)
where w is the mixing ratio, p, is the waterv a p o r density, and p is the total density of the atmosphere. Spectroscopic observations yield the total a m o u n t of water v a p o r above a given effective level, which is equivalent to f "~ p~ dz,
with units of gm cm 2. The results of several such observations are shown in Table I. I t 1This work was supported by the National m a y be noted that B o t t e m a et al. (1965) Aeronautics and Space Administration under Con give two different values based upon two tract NASw1227. different reflecting levels. These reflecting 329
330
GEORGE
OH~ING
evels are based upon the estimates of the cloudtop pressure given b y Sagan and Kellogg (1963): 90 to 600 mbar. Spinrad (1962) gives only an upper limit to the possible amount of water vapor. Furthermore, Spinrad's observation refers to the total amount of water vapor above a level deep in the atmosphere. Dollfus' (1963) estimate of 1 X 10~ gm cm 2 is based upon
and Dollfus (1963) are shown with the label k = 0. Spinrad's own estimate of the nmximum watervapor mixing ratio, 10~, is also shown. These values are to be compared with the saturation mixing ratio at the temperature of the cloudtop. The saturation mixing ratio is
TABLE 1
where 'mv/m is the ratio of the molecular weight of water vapor to the molecular weight of the Cytherean atmosphere, and e~ is the saturation vapor pressure, which depends upon the temperature of the cloudtop. If we assume that the molecular weight of the Cytherean atmosphere is equal to that of nitrogen, we find m ~ / m = 0.64. The 813 u thermal emission observations of Sinton and Strong (1960) suggest a cloud temperature at unit optical depth of about 235°K. Chamberlain (1965), after applying a correction for scattering, suggests an upper limit of about 255°K for the cloudtop temperature. The 814 ~ thermal emission observations of M u r r a y et al. (1963) indicate a cloud temperature of 208°K, but they state that their observed temperatures are systematically too low because of uncertain telescope transmission losses. Pollack and Sagan (1965) have evaluated in detail several models of the atmosphere and clouds in an attempt to explain the observed limbdarkening of Venus in the 813 t~ interval. T h e y suggest a convective cloud nmdel, in which the limbdarkening is caused by absorption and scattering within the clouds, as the most likely explanation of the observed limbdarkening. For reasonable values of the parameters in this model, and based upon an overall disc temperature at 813 t~ as measured b y Sinton and Strong (1960), cloudtop temperatures of about 210°K are obtained. Thus, as the above discussion indicates, there is, at present, some uncertainty in the value of the cloudtop temperature. The lines in Figs. 1 and 2 show the variation of saturation mixing ratio with temperatures as the cloudtop temperature varies from 210 ° to 235°K. The constant mixing ratios (k = 0) are clearly at least an order of magnitude less than the saturation mixing ratio at a cloudtop temperature of
OBSERVATIONS OF W A T E R VAPOR ON VENUS Presumed reflecting level (mbar)
pvdz (gm/cm:)
Investigators
Spinrad (1962) Dollfus (1963)
<7 X 10:~ 1 X 10 2
Bottema et al. (1965)
1.23 X 102 2.9 X 10~
8000 90 6OO 90 600
an assumed reflecting level somewhat lower than 1 arm. For purposes of these computations, we have assigned values of 90 and 600 mbar to associate with Dollfus' observations. There is some uncertainty in the reflecting levels assumed by Dollfus and by Bottema et al.; their observations m a y refer to reflecting levels somewhat deeper in the atmosphere than the level of the cloudtop; on the other hand, Spinrad's abundances are relatively pressureinsensitive. If it is assumed that the water mixing ratio is constant with altitude, its value can be obtained as follows. From the definition of mixing ratio we have p~ =
(2)
wp.
Integrating both sides with respect to height, and using the hydrostatic equation, we have p~ d z = w
p dz =
_w
(3)
where p~ is the pressure at the effective reflecting level, and g is the gravitational acceleration. The mixing ratio can then be written as /\g/
In Figs. 1 and 2, the results of such computations for the data of Bottema et al. (1965)
w~ = ( m , / m ) ( e , / p ) , ,
(5)
CLOUDTOPS
OF
331
VENUS or~*,a9lol'
I
I
I
I
,o,_
I
)  o
,.
! ~D
_z _x
o°0o,,oo,
w
]
[3 Bottemo, et ol
5
21
J
SpinroL
215
220 CLOUD
I
I
,I.
225
230
235
TOP T E M P E R A T U R E
k
(°K)
Fro. 1. Watervapor mixing ratios at the Cytherean c]oudtop for a eloudtop pressure of 90 mbar. Solid line represents mixing ratios required for saturation; points represent mixing ratios computed from observations.
I
I
I
oloan~oe ]
I
jO4 O
k = 0.56
k
.~
~. I0~
g
w o Bottema, et al $pinrod

IO 210
I
215
I
220 CLOUDTOP
I
225 TEMPERATURE
I
230
I
255
('K)
Fro. 2. Watervapor mixing ratios at the Cytherean cloudtop for a cloudtop pressure of 600 mbar. Solid line represents mixing ratios required for saturation; points represent mixing ratios computed from observations.
332
GEORGE
235°K, and also less than the saturation values at cloudtop temperatures as low as 215°K. On the basis of similar computations, Sagan and Kellogg (1963) and Chamberlain (1965) have questioned the aqueous nature of the Cytherean clouds. Gutnick (1962) has analyzed the variation of watervapor mixing ratio with altitude at middle latitudes in the Earth's atmosphere. In the troposphere, the average mixing ratio decreases logarithmically with altitude. Such a decrease can be represented by d In w/dz =  k.
(6)
Gutnick's data indicate that the average value of k is about 0.375 km ~ between the surface and 7 kin, and about 0.56 km 1 between 7 and 14 km. If we assunle similar variations of mixing ratio with altitude above the Cytherean clouds, keeping the total watervapor amount consistent with the observations, what mixing ratios would we obtain at the cloudtop? We have .,
=
(7)
woe ~
for the variation of mixing ratio above the clouds. (For constant mixing ratio, /¢ = 0.) The variation of watervapor density with altitude can then be written as
(8)
p,, = p ( p J p ) o ~  %
where the subscript zero refers to the cloudtop. The variation of atmospheric density with altitude is here assumed as that for an isothermal atmosphere.
(9)
p = poe'%
where H is the scale height. For atmosphere with a temperature and g = 880 cm/sec 2, H = 7.9 stituting Eq. (9) into Eq. (8), we
a nitrogen of 235°K kin. Subhave
p,, = (p,)0 exp [(0.127 + k)z].
(10)
The integral of Eq. (10) with respect to height must be equal to the observed total amount of water vapor above the cloud,
/o
p,
dz = (p~)0
/o
exp [ (0.127 + k)z]. (ll)
OHRING
Integrating the righthand side of Eq. (11) and solving for (p~)o, we find (p,)0 = (0.127 + k)
p~dz.
(12)
The mixing ratio at the cloudtop can then be obtained fronl (p~/p)o, where p0 is computed from
po = rap~R'T,
(13)
where p and T are the pressure (90 and 600 mbar) and approxinlate temperature (235°K) at the cloudtop, and R* is the universal gas constant. Cloudtop mixing ratios computed in this manner for the data of Bottema et al. (1965) and Dollfus (1963) are shown in Figs. 1 and 2, where they are labeled k = 0.375 and k  0.56. Spinrad's data are not treated in this way since if one were to assume an exponential decrease of watervapor mixing ratio above his presumed reflecting level of 8000 mbar, the computed watervapor mixing ratios at 90 or 600 mbar would be less than that computed for the assumption of constant mixing ratio, and, hence, would depart further from the required saturation mixing ratio. Thus, no matter what assumption is made about the variation of water vapor with altitude, Spinrad's data appear to be incompatible with an aqueous cloud, if his observations are referred to the 8000mbar level. It is apparent from Figs. 1 and 2 that these mixing ratios are much closer than the constant mixing ratios to the required saturation mixing ratios at a cloudtop temperature of 235°K. And if the actual cloudtop temperature were just 510°C lower, saturation would actually occur for some of these cases. Thus, at least for the observations of Bottema et al. (1965) and Dollfus (1963), the observed watervapor amounts are compatible with an ice crystal cloud if the cloudtop temperature is 225 ° to 230°K or less, and the watervapor mixing ratio decreases with altitude at a rate comparable to that in the Earth's upper troposphere. III. CONCLUS,ON,~ There is no reason to believe that the assumption of a constant mixing ratio above the Cytherean cloud is better than the
CLOUDTOPS OF VENUS
assumption of a logarithmic decrease. I n fact, a better case can be made for the assumption of a logarithmic decrease since, if the clouds are composed of water substance, the variation of mixing ratio with altitude might be similar to that observed above terrestrial clouds. A reasonable estimate of such a variation is the average value of the upper tropospheric variation of mixing ratio in the E a r t h ' s atmosphere. As indicated above, this value leads, under certain conditions, to cloudtop mixing ratios compatible with the presence of clouds composed of water substance. Thus, we m a y conclude that compatibility between the observed watervapor amounts and the presence of water clouds on Venus can be achieved under certain conditions. Or, put another way, the observed watervapor amounts, at the present state of our knowledge, are not incompatible with the presence of water clouds on Venus. REFERENCES BOT~MA, M., et al. (1964). Composition of the clouds of Venus. Asirophys. J. 139, 10211022.
333
BOm~MA, M., et al. (1965). A quantitative measurement of water vapor in the atmosphere of Venus. Ann. Astrophys. 28, 225228. CHAMBERL~N, J. W. (1965). The atmosphere of Venus near her cloud tops. Astrophys. J. 141, 11841205. DOLLFUS, A. (1963). Observation of water vapor on the planet Venus. Compt. Rend. 256, 32503253. Gu'rNIcK, M. (1962). Mean annual midlatitude moisture profiles to 31 km. Air Force Surveys in Geophysics 147, 30 pp. (Air Force Cambridge Res. Lab.). MURRAY,B. C. et al. (1963). Infrared photometric mapping of Venus through the 8 to 14micron atmospheric window. J. Geophys. Res. 68, 48124818. POLLACK, J. B., AND SAGAI~T, C. (1965). The infrared limb darkening of Venus. J. Geophys. Res. 70, 44034426. SAGAN, C., AND KELLOg, W. W. (1963). The terrestrial planets. Ann. Rev. Astron. Astrophys. 1, 235266. SINTON, W. M., aND STRONG, J. (1960). Radiometric observations of Venus. Astrophys. J. 131, 470490. SPINaAV, H. (1962). A search for water vapor and trace constituents in the Venus atmosphere. Icarus 1, 266270.